A CARS investigation of HBr and H2 collisions with hot H atoms produced by ArF laser photolysis of HBr
- 15 July 1983
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 79 (2), 759-764
- https://doi.org/10.1063/1.445826
Abstract
Coherent anti‐Stokes Raman spectroscopy is used to examine the rotational and vibrational state distributions in HBr and H2 molecules excited by collisions with translationally hot H atoms produced by ArF laser photolysis of HBr. CARS detection of Br atoms and of rovibrationally excited H2 produced by the H+HBr reaction is demonstrated for the first time.Keywords
This publication has 13 references indexed in Scilit:
- Evidence for high rotational excitation in CO produced by collisions with hot H atoms formed in the photodissociation of HBrThe Journal of Chemical Physics, 1982
- A sensitive, non-intrusive point diagnostic for atomic chlorine using coherent anti-stokes Raman scatteringChemical Physics Letters, 1982
- Picosecond cars as a probe of the multiphoton photofragmentation of benzeneChemical Physics Letters, 1981
- Kinetic study of the reactions of hydrogen and deuterium atoms with HBr and DBr by time-resolved resonance fluorescenceJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1980
- CARS spectra of combustion gasesCombustion and Flame, 1979
- Production of electronically excited atoms. H + Br2 → HBr + Hb(*), H + HBr → H2 + Br(*)Chemical Physics Letters, 1979
- A Review of the Theory and Application of Coherent Anti-Stokes Raman Spectroscopy (CARS)Applied Spectroscopy, 1977
- Reactions of atomic hydrogen and deuterium with hydrobromic acid and hydrobromic acid-dThe Journal of Physical Chemistry, 1976
- Trajectory study of reactions in HBr–Br2 systemsThe Journal of Chemical Physics, 1973
- Hot Atom Reactions in the HBr–Br2, DBr–Br2 SystemsThe Journal of Chemical Physics, 1972