Universal diffusion-limited colloid aggregation

Abstract

The authors study the process of diffusion-limited colloid aggregation (DLCA) using both static and dynamic light scattering. Static light scattering is used to measure the fractal dimension of the clusters as well as their structure factor, which is found to be in good agreement with that obtained from calculation using computer-generated clusters. Dynamic light scattering is used to probe both translational and rotational diffusion motion of the clusters. A method to separate their respective contributions is developed, allowing a quantitative determination of the average hydrodynamic radius. In addition, they determine the ratio of the hydrodynamic radius to the radius of gyration for individual aggregates, and find beta =0.93. A method is developed to scale all the dynamic light scattering data onto a single master curve, whose shape is sensitive to key features of the DLCA process. Good agreement is found between the prediction of the shape of the master curve and that obtained from experiments. Using several completely different colloids, they find that the shape of their master curves are identical, their fractal dimensions are identical and their aggregation kinetics are identical. This provides strong evidence of the universality of the DLCA regime of colloid aggregation.