Redox switchable NIR dye derived from ruthenium–dioxolene–porphyrin systems
- 14 October 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 22,p. 2648-2649
- https://doi.org/10.1039/b206000k
Abstract
Newly synthesised Ru(bp)2(sq)+-derivatives, covalently linked to a porphyrin-core, show very high ε values in the NIR region; which exhibit fast on/off switching depending on the redox state of the coordinated dioxolene functionality.Keywords
This publication has 13 references indexed in Scilit:
- Kinetics of oxidation of ascorbic acid and 1,4-dihydroxybenzene by semiquinone radical bound to ruthenium(ii)J. Chem. Soc., Dalton Trans., 2002
- Non-innocent behaviour in mononuclear and polynuclear complexes: consequences for redox and electronic spectroscopic propertiesJ. Chem. Soc., Dalton Trans., 2002
- Fully Conjugated Porphyrin Tapes with Electronic Absorption Bands That Reach into InfraredScience, 2001
- Novel oxidation and reduction products of the neutral nickel-dithiolene Ni(Pr2itimdt)2 (Pr2itimdt is the monoanion of 1,3-diisopropylimidazolidine-2,4,5-trithione)Inorganica Chimica Acta, 1998
- Synthesis of Novel Heteroquaterphenoquinones and Their Electrochemical, Structural, and Spectroscopic CharacterizationThe Journal of Organic Chemistry, 1996
- Near-infrared absorbing dyesChemical Reviews, 1992
- Syntheses and properties of pyridocarbazole quinonoid-type near-infrared colour formersJournal of the Chemical Society, Chemical Communications, 1992
- Optimization of parameters for semiempirical methods I. MethodJournal of Computational Chemistry, 1989
- An AM1 theoretical study of the structure and electronic properties of porphyrinThe Journal of Organic Chemistry, 1988
- Catechol-quinone redox series involving bis(bipyridine)ruthenium(II) and tetrakis(pyridine)ruthenium(II)Inorganic Chemistry, 1986