An accurate spectrophotometer for measuring the transmittance of solid and liquid materials

Abstract

The optical transmittance of solids and liquids as well as the molar absorptivity of various chemical species are parameters of fundamental significance in characterizing these materials. Meaningful transmittance data can be obtained only when the measurements are performed with well-known accuracy and precision. To perform such measurements, a high accuracy spectrophotometer was designed and assembled at NBS, Analytical Chemistry Division, and will be described in this paper. This single-beam instrument is composed of a constant radiation source, a monochromator, a sample carriage, an integrating sphere-photomultiplier assembly followed by appropriate electronics, and a read out system consisting of a digital voltmeter and a computer data acquisition and handling provision. The accuracy of transmittance measurements is determined by the light-addition principle used in conjunction with a two-aperture arrangement. The spectrophotometer can be used in manual or automatic modes of operation. A detailed discussion of the data obtained with this instrument, used in both modes, will be presented together with its application to the certification of solid and liquid Standard Reference Materials for checking the photometric scales of conventional spectrophotometers.