Zur Darstellung und Struktur des 1.3-Dichloro-5-N.N-dimethylamino-1.3-dithia-2.4.6-triazins / Synthesis and Structure of 1,3-Dichloro-5-N,N-dimethylamino-1,3-dithia-2,4,6-triazine

Abstract

The six membered ring of composition (CH₃)₂NCN₃S₂Cl₂ 3 a was prepared from N,N-dimethylguanidinhydrochloride and trithiadiazindichloride. 3 a was characterized on the basis of mass, ¹H, ¹³C NMR spectra and X-ray structure analysis. Crystals of 3 a are monoclinic, space group P2₁/c, with a = 660.3(6), b = 834.5(7), c = 1774.7(15) pm, β = 112.83(6)° and Z = 4. The C₂N unit lies approximately in the plane of the [-CNSNSN-] ring, with both Cl atoms on the same side of the ring.