A Catalyst for Efficient and Highly Enantioselective Hydrogenation of Aromatic, Heteroaromatic, and α,β-Unsaturated Ketones
- 1 December 2000
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 2 (26), 4173-4176
- https://doi.org/10.1021/ol000309n
Abstract
PhanePhos-ruthenium-diamine complexes catalyze the asymmetric hydrogenation of a wide range of aromatic, heteroaromatic, and alpha, beta-unsaturated ketones with high activity and excellent enantioselectivity.Keywords
This publication has 16 references indexed in Scilit:
- General Asymmetric Hydrogenation of Hetero-aromatic KetonesOrganic Letters, 2000
- Selective Hydrogenation of Benzophenones to Benzhydrols. Asymmetric Synthesis of Unsymmetrical DiarylmethanolsOrganic Letters, 2000
- Rapid, productive and stereoselective hydrogenation of ketonesPure and Applied Chemistry, 1999
- Titanocene-Catalyzed Asymmetric Ketone Hydrosilylation: The Effect of Catalyst Activation Protocol and Additives on the Reaction Rate and EnantioselectivityJournal of the American Chemical Society, 1999
- Conformationally Flexible Biphenyl-phosphane Ligands for Ru-Catalyzed Enantioselective HydrogenationAngewandte Chemie International Edition, 1999
- Asymmetric Hydrogenation of Alkenyl, Cyclopropyl, and Aryl Ketones. RuCl2(xylbinap)(1,2-diamine) as a Precatalyst Exhibiting a Wide ScopeJournal of the American Chemical Society, 1998
- Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium ComplexesAccounts of Chemical Research, 1997
- Stereoselective Hydrogenation of Simple Ketones Catalyzed by Ruthenium(II) ComplexesThe Journal of Organic Chemistry, 1996
- Preferential hydrogenation of aldehydes and ketones.Journal of the American Chemical Society, 1995
- Practical Enantioselective Hydrogenation of Aromatic KetonesJournal of the American Chemical Society, 1995