SOME OBSERVATIONS ON THE STRUCTURE OF ETHYLENETHIURAM MONOSULPHIDE
- 1 December 1960
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 38 (12), 2349-2358
- https://doi.org/10.1139/v60-318
Abstract
An attempt has been made to answer several apparent objections to the structure ethylene-thiuram monosulphide assigned to the monomeric material of formula C4H6N2S3 obtained by air oxidation of disodium ethylenebisdithiocarbamate. Comparison of the ultraviolet and infrared absorption spectra, potentiometric titrations, and biological assays of the compound and several heterocyclic and other compounds containing the N–C–S grouping has eliminated two possible alternative structures containing thiadiazolidine and dithiazolidine ring systems and has led to the conclusion that the original assignment of structure was correct.Keywords
This publication has 8 references indexed in Scilit:
- Anmerkung zu den ultravioletten Spektren von Verbindungen mit C=S-GruppenCollection of Czechoslovak Chemical Communications, 1959
- THE INTERACTION BETWEEN DISODIUM ETHYLENEBISDITHIOCARBAMATE (NABAM) AND MANGANESECanadian Journal of Botany, 1958
- The Structure and Antimicrobial Activity of Some Isothiocyanate Oxides and Sulfides1Journal of the American Chemical Society, 1958
- Tetrabutylammonium Hydroxide as Titrant for Acids in Nonaqueous SolutionsAnalytical Chemistry, 1956
- Tetrabutylammonium Hydroxide as Titrant in Nonaqueous MediaAnalytical Chemistry, 1956
- THE AERATION PRODUCTS OF DISODIUM ETHYLENEBISDITHIOCARBAMATECanadian Journal of Chemistry, 1954
- Infrared Spectra and Tautomerism of 2-Thioöxazolidone and CongenersJournal of the American Chemical Society, 1950
- STUDIES ON THE MECHANISM OF FUNGICIDAL ACTIONAnnals of Applied Biology, 1942