Titanium (III) Reduction of Sulfoxides
- 1 January 1973
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 3 (1), 37-38
- https://doi.org/10.1080/00397917308062000
Abstract
Titanium (III) chloride is a mild and effective reagent for the generation of carbonyl compounds from oximes1 and nitroalkanes2. Imines have been posutlated as the intermediates which undergo in situ hydrolysis to afford the final products.Keywords
This publication has 3 references indexed in Scilit:
- Chemistry of sulfoxides and related compounds. XXXVII. Reduction of sulfoxides with sodium hydrogen sulfiteThe Journal of Organic Chemistry, 1972
- Mild procedure for transforming nitro groups into carbonyls. Application to the synthesis of cis-jasmoneJournal of the American Chemical Society, 1971
- The reduction of oximes with tervalent titanium, a mild deoximation procedure and the partial synthesis of erythromycylamine.Tetrahedron Letters, 1971