One-Pot Synthesis of Core-Expanded Naphthalene Diimides: Enabling N-Substituent Modulation for Diverse n-Type Organic Materials
- 9 December 2011
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 14 (1), 292-295
- https://doi.org/10.1021/ol203059r
Abstract
A mild and versatile one-pot synthesis of core-expanded naphthalene diimides has been developed, which undergoes a nucleophilic aromatic substitution reaction and then an imidization reaction, allowing an easy and low-cost access to diverse n-type organic materials. Some newly synthesized compounds by this one-pot operation exhibited high electron mobility of up to 0.70 cm(2) V(-1) s(-1) in ambient conditions.Keywords
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