Reaction of hexafluorobut-2-yne with nickelocene and the crystal structure of [C5H5NiCF3CCCF3]4

1 January 1973

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 22,p. 865-866
https://doi.org/10.1039/c39730000865

Abstract

Reaction of CF₃CCCF₃ with (π-C₅H₅)₂Ni gives C₆(CF₃)₆, C₅H₅Ni[C₅H₅(CF₃CCCF₃)₂], [C₅H₅NiCF₃CCCF₃]₄, and C₅H₅)₂Ni₃(CF₃CCCF₃)₃ in addition to known products; the molecular structure of [C₅H₅NiCF₃CCCF₃]₄ has been determined by X-ray analysis.

Keywords

HEXAFLUOROBUT
YNE
NICKELOCENE
RAY ANALYSIS
KNOWN PRODUCTS
Π C5H5
MOLECULAR STRUCTURE
CRYSTAL STRUCTURE

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