Ultraviolet Reflection Spectrum of Cubic CdS
- 18 October 1965
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 140 (2A), A633-A637
- https://doi.org/10.1103/physrev.140.a633
Abstract
The normal-incidence reflection spectrum of cubic CdS has been measured for photon energies between 2 and 22 eV. The samples were prepared by epitaxial deposition on the {1¯11} "As face" of GaAs. The lowest direct absorption edge produces a reflection peak at 2.50 eV at room temperature. The peak (at 5.49 eV) does not show the splitting characteristic of hexagonal (wurtzite-type) material. The peak previously reported for wurtzite-type CdS at 7.12 eV is absent in cubic CdS. All other features of the reflection spectra of cubic and hexagonal CdS are very similar. The mixed cubic-hexagonal nature of CdS films deposited on the {1¯11} "P face" of GaP is easily detected with the help of the reflection spectrum: The split component of the peak and the peak appear less intensely than in pure hexagonal CdS. The preparation and epitaxy of cubic and hexagonal CdS films are described and interpreted.
Keywords
This publication has 13 references indexed in Scilit:
- Optical Properties and Band Structure of Wurtzite-Type Crystals and RutilePhysical Review B, 1965
- THE GROWTH OF WURTZITE CdTe AND SPHALERITE TYPE CdS SINGLE-CRYSTAL FILMSApplied Physics Letters, 1965
- Ultraviolet Absorption of Insulators. II. Partially Ionic CrystalsPhysical Review B, 1964
- On the Etching of II–VI and III–V CompoundsJournal of the Electrochemical Society, 1964
- Fundamental Reflectivity and Band Structure of ZnTe, CdTe, and HgTePhysical Review B, 1963
- Refractive Indexes of Single Hexagonal ZnS and CdS CrystalsJournal of the Optical Society of America, 1963
- Reflectivity of Semiconductors with Wurtzite StructurePhysical Review B, 1963
- Exciton Spectrum of Cadmium SulfidePhysical Review B, 1959
- Simplified LCAO Method for Zincblende, Wurtzite, and Mixed Crystal StructuresPhysical Review B, 1959
- Fundamental Absorption Edge in Cadmium SulfidePhysical Review B, 1958