Orbital-Angular-Momentum Decomposition of the Three-Body Coupling Scheme: Muonic Molecules and the Hydrogen Molecular Ion

Abstract

In obtaining the wave functions of three-body Coulomb systems in which two heavy equally charged, and one light oppositely charged, particles are involved, one can use a type of Born-Oppenheimer coupling scheme, to obtain nonadiabatic effects. In this paper we decompose the coupled differential equations of such a scheme in terms of the total orbital angular momentum and parity of the states, and reduce these equations to one-dimensional ones in a form suitable for calculation.