Infrared spectroscopy of interfaces in amorphous hydrogenated silicon/silicon nitride superlattices

Abstract
Infrared and atomic composition measurements of a‐Si: H/a‐SiNx: H superlattices as a function of repeat distance show ∼1×1015 cm2 extra hydrogen bonded to Si at the interface formed when a‐Si:H is deposited on a‐SiNx: H. The H distribution peaks in the first monolayer and decays in the a‐Si:H layer over a distance of ∼19 Å. The hydrogen relieves the large lattice mismatch between the two layers and pacifies defects.