Emission Energy Correlates with Inverse of Gold−Gold Distance for Various [Au(SCN)2]- Salts
- 13 December 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (1), 12-13
- https://doi.org/10.1021/ja037012f
Abstract
A series of bis(thiocyanato)gold(I) complexes with Au-Au interactions show luminescence in the range from 500 to 670 nm. The series of salts correlates emission energy with the reciprocal of the Au-Au distance. As the Au-Au distance increases, the emission energy decreases. The ligand system provides no framework for the Au-Au interaction. The emission energy seems totally determined by the Au-Au distance.Keywords
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