Spectroscopic Evidence for Pressure-Induced Coordination Changes in Silicate Glasses and Melts

Abstract

Infrared spectra demonstrate that at pressures above 20 gigapascals and room temperature the regular tetrahedral coordination of oxygen around both silicon and aluminum ions is severely disrupted in SiO₂, CaMgSi₂O₆, and CaAlSi₂O₈ composition glasses. The spectra are consistent with gradual, pressure-induced increases in the coordination numbers of silicon and aluminum. A variety of coordination environments, from sixfold to fourfold, appears to be present at pressures as high as about 40 gigapascals. This apparent change in coordination is not quenchable at room temperature: on decompression, the glasses return to tetrahedral coordination. This continuous and reversible coordination change in amorphous silicates explains the lack of observation of coordination changes in silicate glasses quenched from high pressure, the shallow melting slopes observed for mantle silicates at high pressures, and the possible presence of neutrally buoyant magmas deep within the terrestrial planets.