The rotational distribution in the mercury hydride molecules (X 2Σ+1/2;v″=0) produced in the reactions Hg(6 3P1)+H2, HD, or D2
- 1 July 1986
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 85 (1), 280-285
- https://doi.org/10.1063/1.451654
Abstract
Initial rotational distributions of the vibrationless HgH or HgD molecules produced in the exoergic reactions of Hg (3P1) with H2, D2, and HD have been determined. No isotope effects have been observed. In the case of the reaction with HD the ratio [HgH(v‘=0)]/[HgD (v‘=0)] as well as the summed over all v‘ ratio [HgH]/[HgD] have been measured.Keywords
This publication has 16 references indexed in Scilit:
- Orbitally selective chemical reaction in Hg–H2 van der Waals complexesThe Journal of Chemical Physics, 1986
- Triplet vs. singlet reactivity of 3s13p1 states of magnesium on molecular hydrogen. A theoretical ab initio SCF-CI investigationThe Journal of Physical Chemistry, 1985
- An ab initio study of the reaction Be(3P) +H2(1Σg+) → BeH(2Σ+)+H(2S)The Journal of Chemical Physics, 1983
- Quenching of excited cadmium(1P1) atoms by several molecules. Cross sections and chemical and physical exit channelsThe Journal of Physical Chemistry, 1978
- Further mercury(3P1) quenching cross sectionsThe Journal of Physical Chemistry, 1975
- Absolute quenching cross sections of Hg(3P1) with various moleculesThe Journal of Physical Chemistry, 1974
- Flash spectroscopy with mercury resonance radiation. Part 3.—An experimental method with a multielectrode flash-lamp. Mercury hydride yieldsJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1972
- Quenching and Depolarization of Mercury Resonance RadiationCanadian Journal of Physics, 1971
- Flash spectroscopy with mercury resonance radiation. Part 2.—Role of HgH in Hg(63P1) sensitized reactionsTransactions of the Faraday Society, 1970
- ber Zerlegung von Wasserstoffmolek len durch angeregte QuecksilberatomeThe European Physical Journal A, 1922