Fruits of Serendipity in Research of Titanium Compounds: from “Sodium Tianide” to Titanium Nitride Whiskers
- 1 September 1988
- journal article
- research article
- Published by Cambridge University Press (CUP) in Powder Diffraction
- Vol. 3 (4), 240-241
- https://doi.org/10.1017/s0885715600013543
Abstract
The usefulness of complementing the results of X-ray diffraction (XRD) with an independent technique such as Raman spectroscopy (RS) was demonstrated by the successful identification of the products (TiN and Na-titanates) from the reaction of TiO2 with NaCN. The study of other reactions of NaCN with several Ti-compounds to produce TiN powder led to the development of new syntheses reactions for known [TiP2O7, NaTi2(PO4)3 and NaxTiO2] and for new [(TiO)2P2O7, Na(TiO)PO4 and Na4(TiO)(PO4)2] compounds. The reaction of NaxTiO2 with NaCN produced TiN in the form of whiskers.Keywords
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