Metal-metal double bond formation and control of cluster geometry via steric design: syntheses and structures of the first Ir4 arsenido and phosphido comlexes; planar unsaturated [Ir(.mu.-tert-Bu2As)](.mu.-CO)2(CO)2(CO)2(Ir:Ir) and tetrahedral saturated [Ir(.mu.-Cy2P)CO]4(.mu.-CO)2, (Cy = cyclohexyl)