Grain-size effects on dielectric properties in barium titanate ceramics

Abstract

Measurements of the dielectric constant κ in high‐purity BaTiO₃ ceramics as a function of temperature show that κ is quite dependent on grain size in the ferroelectric state while it is almost independent of grain size in the paraelectric state. In the ferroelectric orthorhombic and rhombohedral phases, κ decreases rapidly with lowering temperature when grain size is reduced smaller than 3 μm. It is also observed that the Curie temperature T_c is decreased very slightly, but the lower two transition points are shifted to higher temperatures as grain size decreases.