Mixed-Valence Square Planar Complexes: A New Class of Solids with High Electrical Conductivity in One Dimension
- 15 February 1971
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 26 (7), 371-373
- https://doi.org/10.1103/physrevlett.26.371
Abstract
Square planar complexes of platinum are shown to have high, possibly metallic conductivity along one axis due to overlap between orbitals of platinum in two valence states. The room-temperature Seebeck effect is small and positive which is interpreted as caused by a degenerate gas of holes.
Keywords
This publication has 6 references indexed in Scilit:
- Ultraviolet spectral assignments in the tetracyano complexes of platinum, palladium, and nickel from magnetic circular dichroismJournal of the American Chemical Society, 1969
- Planar Complexes Containing Metal‐Metal BondsAngewandte Chemie International Edition in English, 1969
- Crystal Structure of “Ir(CO)3Cl” = Ir(CO)2.93CI1.07Angewandte Chemie International Edition in English, 1968
- Anisotropic electrical conductivity in metal-organic square planar d8 complexesSolid State Communications, 1968
- Strukturen mit Pt‐Ketten, I. „Violettes”︁ Kaliumtetracyanoplatinat, K2[Pt(CN)4]X0,3 · 2,5 H2O (X = Cl, Br)Zeitschrift für anorganische und allgemeine Chemie, 1968
- Possibility of Synthesizing an Organic SuperconductorPhysical Review B, 1964