Cationic Manganese(I) Dihydrogen and Dinitrogen Complexes Derived from a Formally 16-Electron Complex with a Bis-Agostic Interaction, [Mn(CO)(Ph2PC2H4PPh2)2]+
- 1 January 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 118 (28), 6782-6783
- https://doi.org/10.1021/ja960499q
Abstract
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This publication has 21 references indexed in Scilit:
- Flow Reactors for Preparative Chemistry in Supercritical Fluid Solution: "Solvent-Free" Synthesis and Isolation of Cr(CO)5(C2H4) and (.eta.5-C5H5)Mn(CO)2(.eta.2-H2)Organometallics, 1995
- Synthesis and Characterization of Molybdenum Complexes Containing Diphosphine Ligands of the Type (ArCH2)2PC2H4P(CH2Ar)2 (Ar = C6H4X). Electronic Control of .eta.2-Dihydrogen versus Dihydride Coordination in MoH2(CO){(RCH2)2PC2H4P(CH2R)2}2 (R = Me, Pri, C6H4X) and Implications on the Reaction Coordinate for H2 CleavageInorganic Chemistry, 1994
- Transition Metal Complexation of σ BondsAngewandte Chemie International Edition in English, 1993
- Coordination chemistry of dihydrogenChemical Reviews, 1993
- Neutron structure and inelastic-neutron-scattering and theoretical studies of molybdenum complex Mo(CO)(H2)[(C6D5)2PC2H4P(C6D5)2]2.cntdot.4.5C6D6, a complex with an extremely low barrier to hydrogen rotation. Implications on the reaction coordinate for H-H cleavage to dihydrideJournal of the American Chemical Society, 1993
- Reactions of transition metal dihydrogen complexesCoordination Chemistry Reviews, 1992
- [(3,5-(CF3)2C6H3)4B]-[H(OEt2)2]+: a convenient reagent for generation and stabilization of cationic, highly electrophilic organometallic complexesOrganometallics, 1992
- Catalytic thermal carbon-hydrogen activation with manganese complexes: evidence for .eta.2-H2 coordination in a neutral manganese complex and its role in carbon-hydrogen activationOrganometallics, 1992
- Molecular hydrogen complexes: coordination of a .sigma. bond to transition metalsAccounts of Chemical Research, 1988
- New diphosphine-substituted carbonyl complexes of manganeseJournal of Organometallic Chemistry, 1972