Enantioselective construction of stereogenic quaternary centres via Rh-catalyzed asymmetric addition of alkenylboronic acids to α,β-unsaturated pyridylsulfones
- 1 January 2005
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 39,p. 4961-4963
- https://doi.org/10.1039/b508142d
Abstract
The highly enantioselective construction of all-carbon quaternary stereogenic centres via Rh-catalyzed Chiraphos-mediated conjugate addition of alkenylboronic acids to β,β-disubstituted α,β-unsaturated 2-pyridylsulfones is described.Keywords
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