Notizen: Dehnung einer Metall-Metall-Bindung durch sterische Hinderung Die Kristallstruktur von FeMn(CO)8P(C6H5)2 / Lengthening of a Metal-Metal-Bond by Steric Hindrance The Crystal Structure of FeMn(CO)8P(C6H5)2 1

Abstract

The crystal structure of the title complex 1 shows that its metal-metal bond length is not determined by the radii of the metal or phosphorus atoms but by steric hindrance between vicinal carbonyl groups.