Compounds with vanadium–nitrogen and vanadium–oxygen multiple bonds
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 23,p. 3609-3617
- https://doi.org/10.1039/dt9930003609
Abstract
Vanadium nitrido complexes are generally not accessible by routes successful in rhenium and molybdenum chemistry. The vanadium–nitrogen triple bond is reactive, and easily forms phosphiniminato complexes, two of which [V(NPMe2Ph)Cl3(PMe2Ph)2] and [V(NPMe2Ph)Cl3(PMe2Ph)2]·H2O, have been structurally characterised. The compound [V(NMe)Cl3(py)2](py = pyridine) and related alkylimido species have been synthesised. They can apparently be converted by base to alkylideneamido complexes, but the only material unequivocally and structurally characterised from such systems was [VOCl2(py)2], formed by hydrolysis.Keywords
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