Mechanistic Information from the Effect of Pressure on Thermal and Photochemical Substitution Reactions
- 1 May 1986
- journal article
- research article
- Published by Taylor & Francis in Comments on Inorganic Chemistry
- Vol. 5 (3), 135-153
- https://doi.org/10.1080/02603598608072280
Abstract
The effect of pressure on some typical thermal and photochemical substitution reactions is discussed to illustrate the general applicability of this method in the elucidation of reaction mechanisms. The selected examples include square planar solvolysis, octahedral complex formation, base hydrolysis and photosolvolysis reactions. A critical evaluation is given and general trends are discussed.Keywords
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