The synthesis and transport properties of the complex salt (TMPD) (TCNQ)2
- 1 February 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 62 (3), 1061-1067
- https://doi.org/10.1063/1.430573
Abstract
The syntheses and transport properties of the complex salt (TMPD) (TCNQ)2 are described. At high temperatures (T≳100°K), the complex is a magnetic semiconductor with transport properties intermediate between those found in the highly conducting and poorly conducting TCNQ salts. The complex undergoes a transition below 50−60°K to a state exhibiting singlet−triplet behavior with weakly alternating exchange coupling.Keywords
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