Depolarized Rayleigh scattering and orientational relaxation of molecules in solution. I. Benzene, toluene, and para-xylene
- 15 June 1973
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 58 (12), 5570-5578
- https://doi.org/10.1063/1.1679181
Abstract
Measurements of orientational relaxation rates of benzene, toluene, and para‐xylene in a variety of solvents have been made by depolarized light scattering. A plot of reorientational relaxation time of each solute versus solution viscosity was found to fit a straight line with nonzero intercept. The slopes of the lines are compared with those predicted by the Stokes‐Einstein relation.Keywords
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