A ruthenium heteropolyanion as catalyst for alkane and alkene oxidation

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Abstract
A ruthenium heteropolyanion, SiRu(H2O)W11O39 5–, has been synthesized which catalyses the liquid phase oxidation of alkanes and alkenes with various primary oxidants including potassium persulphate, sodium periodate, t-butyl hydroperoxide, and iodosylbenzene; the activity and selectivity vary with the oxidant used.