Allylsilanes in organic synthesis: a synthesis of prostaglandins
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 79-80
- https://doi.org/10.1039/c39770000079
Abstract
The allylsilane (2) reacts with a variety of electrophiles in the sense shown in Scheme 1; one electrophile, methoxymethyl chloride in the presence of stannic chloride, gives an intermediate (7), which can be converted into prostaglandins.This publication has 1 reference indexed in Scilit:
- Hydrogen and trimethylsilyl migrations in 5-(trimethylsilyl) cyclopentadieneJournal of the American Chemical Society, 1970