One Template Synthesis of Raspberry-like Hierarchical Siliceous Hollow Spheres
- 6 November 2007
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 129 (47), 14576-14577
- https://doi.org/10.1021/ja077110r
Abstract
We report the synthesis of raspberry-like hierarchical siliceous hollow spheres (HSHS) via a one-pot, one template approach. The siliceous species and block copolymer molecules self-assemble simultaneously into composite spherical micelles and vesicles in solution. The colloidal interaction between spheres with different sizes gives rise to the final HSHS structure with a raspberry morphology.Keywords
This publication has 7 references indexed in Scilit:
- Hollow Silica Spheres with an Ordered Pore Structure and Their Application in Controlled Release StudiesChemistry – A European Journal, 2006
- Vesicles and Liposomes: A Self‐Assembly Principle Beyond LipidsAdvanced Materials, 2003
- Fabrication of Highly Conductive 12CaO·7Al2O3 Thin Films Encaging Hydride Ions by Proton ImplantationAdvanced Materials, 2003
- Ordered Mesoporous Silica with Large Cage-Like Pores: Structural Identification and Pore Connectivity Design by Controlling the Synthesis Temperature and TimeJournal of the American Chemical Society, 2002
- Polycationic Peptides from Diatom Biosilica That Direct Silica Nanosphere FormationScience, 1999
- Nanoengineering of Inorganic and Hybrid Hollow Spheres by Colloidal TemplatingScience, 1998
- Oil-Water Interface Templating of Mesoporous Macroscale StructuresScience, 1996