A stable compound with a tin–phosphorus double bond: the (2,4,6-triisopropylphenyl)(supermesityl)stannaphosphene
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1047-1048
- https://doi.org/10.1039/c39920001047
Abstract
The stable bis(2,4,6-triisopropylphenyl)(supermesityl)stannaphosphene 1(supermesityl : 2,4,6-tri-tert-butylphenyl) has been synthesized by dehydrofluorination of the corresponding fluorostannylphosphine by tert-butyllithium; its structure has been evidenced by NMR spectroscopy and by addition of methanol and water onto the tin–phosphorus double bond.Keywords
This publication has 19 references indexed in Scilit:
- Multiple Bonds to SiliconPublished by Wiley ,2004
- Strained‐Ring and Double‐Bond Systems Consisting of the Group 14 Elements Si, Ge, and SnAngewandte Chemie International Edition in English, 1991
- Multiply bonded germanium species. Recent developmentsChemical Reviews, 1990
- Chemistry of the Silicon‐Silicon Double BondAngewandte Chemie International Edition in English, 1987
- A Stable StannaetheneAngewandte Chemie International Edition in English, 1987
- Stable germa- and stannaethenesPublished by Walter de Gruyter GmbH ,1987
- SilenesPublished by Elsevier ,1986
- The Synthesis, Properties, and Reactivities of Stable Compounds Featuring Double Bonding Between Heavier Group 14 and 15 ElementsPublished by Wiley ,1986
- A compound with a tin-phosphorus double bond: the first stable stannaphospheneJournal of the American Chemical Society, 1985
- Multiple bonding to siliconChemical Reviews, 1985