Expeditious Syntheses of α- and β-(1→6-LinkedC-Disacćharides by way of SRN1 Coupling Processes

Abstract

The photolytically-induced cross-coupling of α- and β-glycosylmethyl radicals, generated from the corresponding cobaloximes, with nitronate ions derived from 6-nitro sugars, provides an expeditious approach to α- and β-(1→6)-linked C-disaccharides.