Energies Involved in Reorienting Hydration Shells of Ions
- 1 October 1958
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 29 (4), 851-855
- https://doi.org/10.1063/1.1744600
Abstract
Free energies for reorientation of solvent molecules about ions have been calculated using Marcus' equation for the electrostatic potential and compared with values derived from charge transfer spectra. The low values obtained suggest that electron tunneling between fully hydrated ions is a feasible mechanism contrary to the conclusions of Platzman and Franck.Keywords
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