Adiabatic compressibility and structure of aqueous solutions of methyl-alcohol
- 15 July 1987
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 87 (2), 1251-1255
- https://doi.org/10.1063/1.453307
Abstract
The adiabatic compressibility of methanol–water mixtures has been measured as a function of temperature and of alcohol mole fraction; the measurements were carried out at 10, 15, and 20 °C over the entire range of cosolvent concentration. A simple model, involving the solute–solvent interactions and the molecular aggregation of the solute, is used to explain the observed behavior.Keywords
This publication has 16 references indexed in Scilit:
- Isentropic compressibility behaviour of dilute solutions of ethyl-alcohol in waterIl Nuovo Cimento D, 1986
- Isentropic compressibilities of alcohol-water mixtures at 25°CJournal of Solution Chemistry, 1981
- Thermodynamics of aqueous mixtures of nonelectrolytes. III. Compressibilities and isochoric heat capacities of water-n-alcohol mixtures at 25°CJournal of Solution Chemistry, 1981
- The Adiabatic Compressibility of Nonelectrolyte Aqueous Solutions in Relation to the Structures of Water and Solutions. II.Bulletin of the Chemical Society of Japan, 1973
- The Adiabatic Compressibility of Nonelectrolyte Aqueous Solutions in Relation to the Structures of Water and SolutionsBulletin of the Chemical Society of Japan, 1973
- Ultrasonic velocity in nonelectrolyte-water mixturesThe Journal of Physical Chemistry, 1971
- Volume changes on mixing for binary mixtures of liquidsChemical Reviews, 1971
- The structural properties of alcohol–water mixturesQuarterly Reviews, Chemical Society, 1966
- A Study of Ultrasonic Velocity and Absorption in Liquid MixturesThe Journal of the Acoustical Society of America, 1948
- Supersonics in a Water-Alcohol Mixture and Analysis of Its Intermolecular ActionThe Journal of the Acoustical Society of America, 1948