Oxygen-Carrying Properties of a Simple Synthetic System
- 17 May 1963
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 140 (3568), 809-810
- https://doi.org/10.1126/science.140.3568.809
Abstract
An iridium compound, chloro-carbonyl-bis(triphenylphosphine)-iridium, in solution, takes up molecular oxygen-one molecule per metal atom-which is subsequently recovered by reducing the pressure. The adduct is photosensitive but otherwise stable at ambient temperatures. It is a monomeric molecular complex and probably contains a peroxo group with both oxygens bonded to the same metal atom.Keywords
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