Atomic Layer Epitaxy of ZnS on GaAs Substrates by Metalorganic Molecular Beam Epitaxy

Abstract
ZnS was grown on GaAs (001) substrates by a metalorganic molecular beam epitaxy (MOMBE) technique, using sequential dimethylzinc (DMZ) and hydrogen sulfide (H2S) reactant gas exposures, where these gases were supplied to the substrates after cracking at 950 and 1080°C, respectively. The results show that at a given temperature between 250 and 310°C, the growth rate was observed to be determined by the number of growth cycles, which is typical of atomic layer epitaxy (ALE). In spite of very large lattice mismatch (4.4%) between ZnS and GaAs, ZnS layers grown in an ALE mode showed good surface morphology and exhibited strong near-band-edge photoluminescence.