Trimethylamine complexes of platinum(II) and palladium(II) and their vibrational and proton nuclear magnetic resonance spectra

Abstract

Preparations of the complexes trans-MX₂(NMe₃)₂ and Prⁿ ₄NMX₃NMe₃(MX = PdCl, PtCl, or PtBr) are reported. Their ¹H n.m.r., i.r., Raman, and electronic spectra are recorded and discussed. Complexes with MX = PdBr, Pdl, or Ptl could not be obtained and there was no indication of the parallel formation of Prⁿ ₄NPtCl₃OMe₂.