Regioselective Halogenation and Dimerization of Alkoxynaphthalenes with Alumina- or Kieselguhr-supported Copper(II) Halides†
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Chemical Research
- No. 11,p. 426-427
- https://doi.org/10.1039/a704445c
Abstract
The reaction of 1-alkoxynaphthalenes 1 with alumina-supported copper(II) bromide or copper(II) chloride gave dimers, 4,4′-dialkoxy-1,1′-binaphthyls 3, as major products, and with Kieselguhr-supported copper(II) bromide afforded 1-bromo-4-alkoxynaphthalenes 2, while the reaction of 2-alkoxynaphthalenes 4 with alumina- or Kieselguhr-supported copper(II) bromide gave preferentially 1-bromo-2-alkoxynaphthalenes 5.This publication has 8 references indexed in Scilit:
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