Electron injecting properties have been studied for one of polyquinoxaline (PQx) derivatives. PQx was clarified to be an excellent electron injecting material for electroluminescent (EL) device because it has many advantageous properties such as high electron affinity, good thermal stability, good processability, and sufficiently low refractive index. On the other hand, since poly(p‐phenylenevinylene) (PPV) was known as a good hole injecting material, an EL device with ITO/PPV/PQx/metal type structure was suggested. It was shown that the quantum efficiency of the cell was higher than that of ITO/PPV/metal cell. Related physical and optical properties of PQx derivatives are also investigated.