Lithium Polysulfidophosphates: A Family of Lithium‐Conducting Sulfur‐Rich Compounds for Lithium–Sulfur Batteries
- 4 June 2013
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 52 (29), 7460-7463
- https://doi.org/10.1002/anie.201300680
Abstract
Sulfur-rich lithium polysulfidophosphates (LPSPs) act as an enabler for long-lasting and efficient lithium–sulfur batteries. LPSPs have ionic conductivities of 3.0×10−5 S cm−1 at 25 °C, which is 8 orders of magnitude higher than that of Li2S. The high lithium ion conductivity imparts excellent cycling performance, and the batteries are configured in an all-solid state, which promises safe cycling with metallic lithium anodes.Keywords
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