Direct measurement of the internal electric field distribution in a multilayer organic light-emitting diode

Abstract

We present a general electroabsorption technique to measure the electric field in each layer of multilayer organic light‐emitting diodes. The electroabsorption signal from each layer is identified spectroscopically and measured as a function of dc bias. Measurements were made on three layer devices consisting of a hole transport layer, a light‐emitting layer, and an electron transport layer. In reverse bias, without significant charge injection, the dcelectric field is uniform throughout the device. In forward bias, the dcelectric field is distributed nonuniformly; it is smallest in the light‐emitting layer and largest in the hole transport layer. The nonuniform dcelectric field distribution is caused by the accumulation of electrons (holes) at the interface between the light‐emitting layer and the hole (electron) transport layer. The maximum accumulated charge densities are 2×1012 electrons/cm2 and 3×1011 holes/cm2. These results highlight the carrier blocking role of monopolar transport layers and demonstrate a powerful technique to characterize multilayer organic structures.