AN EFFICIENT GLUCOSYLATION OF ALCOHOL USING 1-THIOGLUCOSIDE DERIVATIVE
- 5 May 1979
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 8 (5), 487-490
- https://doi.org/10.1246/cl.1979.487
Abstract
Glucosides and disaccharides were prepared in good yields from 2-benzothiazolyl 2,3,4,6-tetra-O-benzyl-1-thio-D-glucopyranoside and alcohols including sterically hindered secondary alcohols in the presence of cupric triflate. α-Glucosides were obtained predominantly by this method.Keywords
This publication has 6 references indexed in Scilit:
- A novel synthesis of 1,2-cis-disaccharidesJournal of the American Chemical Society, 1977
- Stéréospecificité des réactions de glycosylation; synthèse de l'isomaltoseCarbohydrate Research, 1976
- Halide ion catalyzed glycosidation reactions. Syntheses of .alpha.-linked disaccharidesJournal of the American Chemical Society, 1975
- Syntheses of α-D-linked disaccharidesCarbohydrate Research, 1975
- Results and Problems of O‐Glycoside SynthesisAngewandte Chemie International Edition in English, 1974
- Solvolytic routes via alkylcopper intermediates in the electron-transfer oxidation of alkyl radicalsJournal of the American Chemical Society, 1972