Estimation of Lennard-Jones (6,12) Pair Potential Parameters from Gas Solubility Data
- 15 October 1971
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 55 (8), 4012-4017
- https://doi.org/10.1063/1.1676694
Abstract
The Lennard‐Jones (6,12) pair potential parameters for solvents can be calculated from gas solubility data by using the scaled particle theory to calculate the work of cavity formation. Values of the hard sphere diameter σ1 and the energy parameter ε1/k at 298.15°K and 1 atm pressure are reported for 39 liquids, polar as well as nonpolar. These parameters are discussed in relation to values determined by other methods.Keywords
This publication has 13 references indexed in Scilit:
- The solubility of gases in liquids I. The solubility of a series of fluorine-containing gases in several non-polar solventsThe Journal of Chemical Thermodynamics, 1971
- Interpretation of solubility data on the n‐alkanes and some other substances in the solvent waterRecueil des Travaux Chimiques des Pays-Bas, 1968
- Scaled-particle theory of dilute aqueous solutionsThe Journal of Physical Chemistry, 1967
- The structural properties of alcohol–water mixturesQuarterly Reviews, Chemical Society, 1966
- Aqueous Solutions of Nonpolar Gases1The Journal of Physical Chemistry, 1965
- Scaled Particle Methods in the Statistical Thermodynamics of FluidsAdvances in Chemical Physics, 1965
- THE SOLUBILITY OF GASES IN LIQUIDS1The Journal of Physical Chemistry, 1963
- CELL POTENTIALS AND GAS SOLUBILITY THEORY1The Journal of Physical Chemistry, 1962
- Aspects of the Statistical Thermodynamics of Real FluidsThe Journal of Chemical Physics, 1960
- The Solubilities of the Rare Gases in some Simple Benzene DerivativesThe Journal of Physical Chemistry, 1958