Properties ofNear thePhase
- 6 July 1964
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 135 (1A), A10-A16
- https://doi.org/10.1103/physrev.135.a10
Abstract
The heat capacity of solid was measured at several constant volumes in the vicinity of the phase. The heat capacity of the phase near the melting line was found to decrease exceptionally rapidly with decreasing molar volume, and the heat capacity of the phase was found to increase with decreasing molar volume. The unusual behavior of the phase is consistent with the existence of anomalous thermal excitations in this phase. The thermal expansion coefficient and the compressibility of the phase were estimated. Their temperature dependences are consistent with the volume dependence of the heat capacity. The triple-point temperatures and the temperature at the solid-liquid boundary were found to be 1.462, 1.773, and 1.763°K, respectively.
Keywords
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