Arenediazonium ion insertion into an iron–phosphine bond; synthesis and crystal structure of [Fe(NO)2{PPh2CH2CH2P(Ph)2NN(C6H4F-p)}][PF6]·OC4H8
- 1 January 1994
- journal article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 7,p. 1161-1162
- https://doi.org/10.1039/dt9940001161
Abstract
The reaction of [Fe(NO)2(dppe)](dppe = Ph2PCH2CH2PPh2) with [N2C6H4F-p][PF6] gave [Fe(NO)2{PPh2CH2CH2P(Ph)2NN(C6H4F-p)}][PF6] X-ray studies on which revealed the formation of a novel chelating ligand bound to iron through phosphine and η2-NN functionalities and resulting from insertion of an arenediazo group into an iron–phosphorus bond.Keywords
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