Lack of Charge Transfer in Aromatic Charge—Transfer Complexes
- 1 August 1964
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 41 (3), 599-601
- https://doi.org/10.1063/1.1725932
Abstract
Halogen pure electrical quadrupole resonance frequencies have been measured in the three 1:1 complexes, CBr4·p-xylene, CCl4·p-xylene, and Br2·benzene. From an examination of the measured frequencies of the complexes and the halogen-containing compounds (CBr, CCl4, and Br2) together with information from the x-ray structure determinations for two of the complexes, it has been concluded that little if any charge transfer exists in the ground state of these complexes.Keywords
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