Correlation lengths and chain sizes in PS/PVME blends: Influence of compressibility, interactions, and monomer structures
- 15 January 1992
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 96 (2), 1644-1647
- https://doi.org/10.1063/1.462150
Abstract
The lattice cluster theory is applied to explain the observed strong concentration dependence of the apparent radius of gyration and the correlation length in polystyrene/poly(vinylmethylether) blends. The analysis emphasizes the importance of using a theory that properly describes blend compressibility, monomer molecular structures, interactions, and local correlations.Keywords
This publication has 13 references indexed in Scilit:
- Effect of monomer structure and compressibility on the properties of multicomponent polymer blends and solutions. 3. Application to deuterated polystyrene [PS(D)]poly(vinyl methyl ether) (PVME) blendsMacromolecules, 1991
- The microphase separation transition in symmetric diblock copolymer melts: A Monte Carlo studyThe Journal of Chemical Physics, 1991
- Light scattering from ternary polymer solutions: an analysis of the apparent radius of gyrationMacromolecules, 1991
- Static structure factors of compressible polymer blends and diblock copolymer melts. 2. Constraints on density fluctuationsMacromolecules, 1991
- Dielectric normal mode process in binary blends of polyisoprene. 1. Excluded volume effect in undiluted binary blendsMacromolecules, 1990
- Thermodynamics of polymer blends of poly(vinyl methyl ether) and polystyreneMacromolecules, 1990
- Lattice theories of polymeric fluidsThe Journal of Physical Chemistry, 1989
- Temperature, composition and molecular-weight dependence of the binary interaction parameter of polystyrene/poly(vinyl methyl ether) blendsPolymer, 1988
- Critical properties of the Flory–Huggins lattice model of polymer mixturesThe Journal of Chemical Physics, 1987
- Conformations of polydisperse polymer solutions : bimodal distributionJournal de Physique, 1981