Differences in the interaction of 1,2,3-triphenylphosphirene with platinum(II) and platinum(0) complexes. Crystal and molecular structures of cis-[PtCl₂(PPhCPhcph)(PEt₃)] and cis-[PtI(PPhMeCPhCPh)(PPh₃)]

1 January 1988

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 17,p. 1156-1158
https://doi.org/10.1039/c39880001156

Abstract

1,2,3-Triphenylphosphirene undergoes only η¹-co-ordination with Pt^II complexes whereas with Pt⁰ centres insertion also occurs to yield phosphaplatinacyclobutene products.

Keywords

MOLECULAR STRUCTURE

Cited by 14 articles

Differences in the interaction of 1,2,3-triphenylphosphirene with platinum(II) and platinum(0) complexes. Crystal and molecular structures of cis-[PtCl2(PPhCPhcph)(PEt3)] and cis-[PtI(PPhMeCPhCPh)(PPh3)]

Abstract

Keywords

Differences in the interaction of 1,2,3-triphenylphosphirene with platinum(II) and platinum(0) complexes. Crystal and molecular structures of cis-[PtCl₂(PPhCPhcph)(PEt₃)] and cis-[PtI(PPhMeCPhCPh)(PPh₃)]