The mechanisms of spin delocalization through sigma bonds delocalization to gamma protons [1]
- 1 May 1973
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 25 (5), 1093-1101
- https://doi.org/10.1080/00268977300100951
Abstract
A study of the mechanisms of spin delocalization to γ hydrogens was conducted by investigating the change in spin density distribution upon geometrical deformation. The mechanisms are expressed in valence bond pictures. The spin densities were calculated using the SCF-MO-INDO method for the propyl radical. An empirical expression for γ-hydrogen hfsc's is proposed.Keywords
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