Sediments of lakes Rotoroa and Rotoiti, South Island, New Zealand

Abstract

The chemistry and mineralogy of the sediments of Lakes Rotoroa and Rotoiti, South Island, New Zealand (41° 51 S, 172° 38 E and 41° 50 S, 172° 50 E respectively) , were studied. In general, the cation exchange properties, element concentrations, and mineral compositions of the sediments show little variation between samples from each lake. However, some nutrient concentrations, notably exchangeable calcium, magnesium, and potassium, and total nitrogen and sulphur, are higher in sediments from weed beds than in sediments underlying deeper water; iron and manganese concentrations tend to show the opposite trend. Concentrations of exchangeable calcium and total nitrogen, sulphur, manganese, and iron generally decrease down the sediment profiles from the sediment/water interface. Differences between lakes, notably higher concentrations of illite and of the elements potassium, aluminium, titanium, and zirconium, and lower concentrations of calcium in the sediments of Lake Rotoiti than in those from Lake Rotoroa, are probably due mainly to the different geological settings rather than to differences in the diagenetic processes operating within the lakes. Mineralogical analyses indicate that the lake sediments are derived mainly from the valleys of the major inflow rivers rather than from the slopes at the sides of each lake.